VGA, DVI, S-Video and other video connectors pinouts  > Apple pinouts
PinSignalDescription
1Ground  
2VSync  
3Hsync  
4Red return  
5Red video  
6Green  
7Green video  
8+5 volts  
9Blue video  
10DDC data  
11DDC clock  
12Ground   
13/Cable detect connected to ground in the display cable 
14Blue return  
14 pin Apple video connector layout
14 pin Apple video connector
According to 1 reports in our database (1 positive and 0 negative) this pinout should be correct.

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Apple iMac video visual pinout:
Apple iMac video diagram
click to enlarge
Source(s) of this and additional information: iMac G5 developer note
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